Intramolecular electron transfer in 4-(dialkylamino)pyrimidines. Study in solutions and supersonic jet

Jerzy Herbich; F. Perez Salgado; Jerzy Karpiuk

doi:10.1007/BF02863357

Intramolecular electron transfer in 4-(dialkylamino)pyrimidines. Study in solutions and supersonic jet

Jerzy Herbich, F. Perez Salgado, Jerzy Karpiuk

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

The dual fluorescence (a andb) of 4-(dialkylamino)pyrimidines (4-DAAP) in solutions is explained in terms of the TICT state model. 4-DAAP form complexes with protic solvents: efficient radiationless depopulation is “switched on” by hydrogen bonding (HB). The photoinduced electron transferMicrosolvation of pretwistedo-methylated compoundsIII andIV by small polar molecules, contrary to more planarI andII, gives rise to the long-wave (probably TICT) fluorescence.

Original language	English
Pages (from-to)	117-131
Number of pages	15
Journal	Proceedings of the Indian Academy of Sciences - Section A
Volume	104
Issue number	2
DOIs	https://doi.org/10.1007/BF02863357
Publication status	Published - Apr 1992
Externally published	Yes

Keywords

CHEMISTRY
Physics
electron transfer
supersonic jet
charge transfer
polar molecules
luminescence
fluorescence
lasers

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10.1007/BF02863357

https://link.springer.com/article/10.1007/BF02863357

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title = "Intramolecular electron transfer in 4-(dialkylamino)pyrimidines. Study in solutions and supersonic jet",

abstract = "The dual fluorescence (a andb) of 4-(dialkylamino)pyrimidines (4-DAAP) in solutions is explained in terms of the TICT state model. 4-DAAP form complexes with protic solvents: efficient radiationless depopulation is “switched on” by hydrogen bonding (HB). The photoinduced electron transferMicrosolvation of pretwistedo-methylated compoundsIII andIV by small polar molecules, contrary to more planarI andII, gives rise to the long-wave (probably TICT) fluorescence.",

keywords = "CHEMISTRY, Physics, electron transfer, supersonic jet, charge transfer, polar molecules, luminescence, fluorescence, lasers",

author = "Jerzy Herbich and \{Perez Salgado\}, F. and Jerzy Karpiuk",

year = "1992",

month = apr,

doi = "10.1007/BF02863357",

language = "English",

volume = "104",

pages = "117--131",

journal = "Proceedings of the Indian Academy of Sciences - Section A",

issn = "0370-0089",

publisher = "Indian Academy of Sciences",

number = "2",

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TY - JOUR

T1 - Intramolecular electron transfer in 4-(dialkylamino)pyrimidines. Study in solutions and supersonic jet

AU - Herbich, Jerzy

AU - Perez Salgado, F.

AU - Karpiuk, Jerzy

PY - 1992/4

Y1 - 1992/4

N2 - The dual fluorescence (a andb) of 4-(dialkylamino)pyrimidines (4-DAAP) in solutions is explained in terms of the TICT state model. 4-DAAP form complexes with protic solvents: efficient radiationless depopulation is “switched on” by hydrogen bonding (HB). The photoinduced electron transferMicrosolvation of pretwistedo-methylated compoundsIII andIV by small polar molecules, contrary to more planarI andII, gives rise to the long-wave (probably TICT) fluorescence.

AB - The dual fluorescence (a andb) of 4-(dialkylamino)pyrimidines (4-DAAP) in solutions is explained in terms of the TICT state model. 4-DAAP form complexes with protic solvents: efficient radiationless depopulation is “switched on” by hydrogen bonding (HB). The photoinduced electron transferMicrosolvation of pretwistedo-methylated compoundsIII andIV by small polar molecules, contrary to more planarI andII, gives rise to the long-wave (probably TICT) fluorescence.

KW - CHEMISTRY

KW - Physics

KW - electron transfer

KW - supersonic jet

KW - charge transfer

KW - polar molecules

KW - luminescence

KW - fluorescence

KW - lasers

U2 - 10.1007/BF02863357

DO - 10.1007/BF02863357

M3 - Article

SN - 0370-0089

VL - 104

SP - 117

EP - 131

JO - Proceedings of the Indian Academy of Sciences - Section A

JF - Proceedings of the Indian Academy of Sciences - Section A

IS - 2

ER -

Intramolecular electron transfer in 4-(dialkylamino)pyrimidines. Study in solutions and supersonic jet

Abstract

Keywords

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